Mechanism and kinetics of thermolysis of ethers modelling the oxygen-methylene ‘bridge’ bonds in coal organic matter

Autor:	V. Yu. Korobkov, E.N. Grigorieva, V. I. Bykov, Igor V. Kalechitz
Rok vydání:	1989
Předmět:	Reaction mechanism Chemistry Thermal decomposition Ether Methylene bridge Analytical Chemistry chemistry.chemical_compound Fuel Technology Chemical bond Computational chemistry Molecule Organic chemistry Reactivity (chemistry) Tetralin
Zdroj:	Journal of Analytical and Applied Pyrolysis. 16:57-73
ISSN:	0165-2370
DOI:	10.1016/0165-2370(89)80036-1
Popis:	The kinetics of the thermolysis of 19 ethers under hydrogen pressure in excess tetralin have been studied. The data obtained make it possible to relate the reactivity and the mechanism of transformations of the ‘bridge’ bonds to the structure of the bridge itself and of the end groups and to the presence of substituents in these groups. For the first time it has been shown that correlation analysis can be used to predict the reactivity of the corresponding model compounds.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8d5074d279d769390438b621dcfb6050 https://doi.org/10.1016/0165-2370(89)80036-1 Zobrazit plný text záznamu