Thermal decomposition of neodymium-loaded cation exchange resin

Autor: William H. Hale
Rok vydání: 1971
Předmět:
Zdroj: Journal of Inorganic and Nuclear Chemistry. 33:1227-1232
ISSN: 0022-1902
DOI: 10.1016/0022-1902(71)80416-5
Popis: Calcination of Nd3+-form, “Dowex”† 50W-X8 resin in air or oxygen yields Nd2O2SO4 at 600–1000°C and Nd2O3 at 1200°C and above. Pyrolysis in vacuum or nitrogen at 1000°C yields carbon and Nd2O2S. Sulfonic acid groups are reduced by the hydrocarbon matrix at ∼400°C, releasing H2S, CO, and CO2. Resin calcination is proposed for preparing californium and curium oxides from ion exchange eluants. Ion exchange eluant containing Nd (as a stand-in for Cf and Cm) and DTPA was acidified to 0·2M HNO3, Nd was absorbed onto H+-form resin, and the resin was calcined to the pure oxysulfate and to the pure oxide. Both products are porous and will dissolve in hot 0·1 M HNO3.
Databáze: OpenAIRE