Design of new electropolymerized polypyrrole films of polyfluorinated Zn(II) and Mn(III) porphyrins: Towards electrochemical sensors

Autor:	Karine Gorgy, Alain Deronzier, Serge Cosnier, Maria Aparecida Carvalho de Medeiros
Rok vydání:	2008
Předmět:	Materials science Inorganic chemistry Bioengineering Electrolyte Electrochemistry Polypyrrole Benzoic anhydride Biomaterials chemistry.chemical_compound Monomer chemistry Mechanics of Materials Cyclic voltammetry Acetonitrile Pyrrole
Zdroj:	Materials Science and Engineering: C. 28:731-738
ISSN:	0928-4931
DOI:	10.1016/j.msec.2007.10.016
Popis:	New Zn (II) and Mn (III) porphyrins functionalized by one and four electropolymerizable pyrrole groups respectively have been synthesized and their electrochemical behavior was characterized in acetonitrile electrolyte. The electrooxidation of these metallopolyfluoroporphyrins has allowed the formation of N-substituted polypyrrole films. The latter exhibit electrochemical behaviors identical to those of the corresponding monomers combined with the conventional electroactivity of the polypyrrole skeleton. Moreover, the potential electrocatalytic properties of Mn (III)-based polypyrrole films in the presence of molecular oxygen and benzoic anhydride have been illustrated by cyclic voltammetry in organic solution. In addition, preliminary experiments have also demonstrated the potentialities of such polymeric films for the electrochemical detection of H2O2 in aqueous media.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8d3172d7a1c4373b596e813deaf54b43 https://doi.org/10.1016/j.msec.2007.10.016 Zobrazit plný text záznamu Full Text from ScienceDirect