Differential heats of dissolution of potassium nitrate in water at 298.15 K near the saturation concentration

Autor: Stanislav Kolařík, Jiří Hostomský, V. Pekárek
Rok vydání: 1983
Předmět:
Zdroj: Collection of Czechoslovak Chemical Communications. 48:1532-1537
ISSN: 1212-6950
0010-0765
DOI: 10.1135/cccc19831532
Popis: Differential heats of dissolution of potassium nitrate in water at 298.15 K were measured on an 8 700 LKB calorimeter over a molality range 3-3.5 mol/kg. The dependence of the differential heat of dissolution, ΔLm (kJ/mol), on the molality can be described over the above range by the relation ΔLm = -33.933 + 3.635m. The value of the endothermic last dissolution heat obtained by extrapolation to the saturation concentration of 3.75 mol/kg was found to be -20.303 kJ/mol, with a standard deviation of 0.37 kJ/mol.
Databáze: OpenAIRE