Violenes as intermediate transformation products of diarylamines in oxidation of polymers

Autor:	I. R. Akhunov, A. P. Griva, E. T. Denisov
Rok vydání:	1975
Předmět:	Polypropylene chemistry.chemical_classification chemistry.chemical_compound Transformation (genetics) chemistry Radical Polymer chemistry Organic chemistry General Chemistry Polymer Polyethylene
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:1097-1100
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00922976
Popis:	In the initiated oxidation of polymers (polyethylene and polypropylene) the diarylamines Ar2NH are converted to the cation-radicals $$Ar_2 N\mathop N\limits_.^ + Ar_2 $$ (violenes), whereas only the nitroxy radicals Ar2NO are formed when hydrocarbons are oxidized under analogous conditions.
Databáze:	OpenAIRE
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