Multiphoton dissociation of two vanadyl compounds

Autor:	D.A. Johnson, A.W. Pryor, A.B. Waugh, J.E. Eberhardt, R.B. Knott
Rok vydání:	1982
Předmět:	chemistry.chemical_compound Frequency selectivity Chemistry General Physics and Astronomy Molecule Vanadium chemistry.chemical_element Infrared multiphoton dissociation Physical and Theoretical Chemistry Photochemistry Uranyl Dissociation (chemistry)
Zdroj:	Chemical Physics Letters. 93:448-452
ISSN:	0009-2614
DOI:	10.1016/0009-2614(82)83219-3
Popis:	The infrared multiphoton dissociation (IRMPD) of the vanadyl β-diketonate, bis(pivaloy1 trifluoroacetone) oxo vanadium (IV). is compared to that of VOCl 3 . The IRMPD of the 48 atom molecule is similar to that of the analogous uranyl β-diketonates. The frequency selectivity suggests a three- or four-fold isotopic effect, but the experimental enrichment is less than 1.06. ln contrast, the VOCl 3 shows inhomogeneous absorption and peak broadening.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8cf43bcf5c400b3ad9991f736fd643bf https://doi.org/10.1016/0009-2614(82)83219-3 Zobrazit plný text záznamu