Cationic polymerization within van der Waals clusters of the form (CH2:R)n+ (R = CH2, CF2, and CHCH3)

Autor:	James F. Garvey, William R. Peifer, Gopalakrishnan Vaidyanathan, M. Todd Coolbaugh
Rok vydání:	1991
Předmět:	Chemistry Van der Waals molecule General Engineering Ion symbols.namesake Chemical physics Ionization Mass spectrum symbols Cluster (physics) Molecule Physical and Theoretical Chemistry van der Waals force Electron ionization
Zdroj:	The Journal of Physical Chemistry. 95:8337-8343
ISSN:	1541-5740 0022-3654
Popis:	The cluster ion mass spectra resulting from electron ionization of van der Waals clusters composed of ethene, 1, 1-difluoroethene or propene molecules were observed as a function of expansion and ionization conditions. Expansion conditions favoring the formation of large neutral clusters lead to the observation of anomalous ion intensity distributions characterized by strong peaking as a function of cluster size. Comparisons are made between the present results and previous observations in both the gas and condensed phases. We propose that the anomalous cluster ion distributions arise as a consequence of the production of molecular (i.e., covalently bonded) ions produced by a series of intracluster addition (polymerication) reactions.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8cce5d40fdf9ad1c7185b57b60c88ca4 https://doi.org/10.1021/j100174a056 Zobrazit plný text záznamu