A five coordination Cu(ii) cluster-based MOF and its application in the synthesis of pharmaceuticals via sp3 C–H/N–H oxidative coupling

Autor: Hanh T.N. Le, Xuan N. T. Duong, Hiep Q. Ha, Ha L. Nguyen, Thuan Van Tran, Thanh N. Truong, Linh Ho Thuy Nguyen, Tan Le Hoang Doan
Rok vydání: 2017
Předmět:
Zdroj: Catalysis Science & Technology. 7:3453-3458
ISSN: 2044-4761
2044-4753
DOI: 10.1039/c7cy00882a
Popis: Herein, a copper metal–organic framework, termed as VNU-18, containing penta-coordinated sites was successfully synthesized and fully characterized. This material was demonstrated to be an efficient heterogeneous catalyst for the oxidative C–H activation via N–H bonds. The optimized conditions are applicable for the synthesis of pharmaceuticals constructed by α-amino carbonyl skeletons.
Databáze: OpenAIRE