A five coordination Cu(ii ) cluster-based MOF and its application in the synthesis of pharmaceuticals via sp3 C–H/N–H oxidative coupling
Autor: | Hanh T.N. Le, Xuan N. T. Duong, Hiep Q. Ha, Ha L. Nguyen, Thuan Van Tran, Thanh N. Truong, Linh Ho Thuy Nguyen, Tan Le Hoang Doan |
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Rok vydání: | 2017 |
Předmět: |
chemistry.chemical_element
02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology Heterogeneous catalysis 01 natural sciences Copper Catalysis 0104 chemical sciences chemistry Polymer chemistry Organic chemistry Oxidative coupling of methane 0210 nano-technology Cluster based |
Zdroj: | Catalysis Science & Technology. 7:3453-3458 |
ISSN: | 2044-4761 2044-4753 |
DOI: | 10.1039/c7cy00882a |
Popis: | Herein, a copper metal–organic framework, termed as VNU-18, containing penta-coordinated sites was successfully synthesized and fully characterized. This material was demonstrated to be an efficient heterogeneous catalyst for the oxidative C–H activation via N–H bonds. The optimized conditions are applicable for the synthesis of pharmaceuticals constructed by α-amino carbonyl skeletons. |
Databáze: | OpenAIRE |
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