Modification of cobalt carbonyl hydroformylation catalysts by silylphosphine ligands

Autor: O. L. Butkova, S. M. Loktev, Yu.B. Kagan, G. A. Korneeva
Rok vydání: 1985
Předmět:
Zdroj: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 34:1565-1567
ISSN: 1573-9171
0568-5230
Popis: The introduction of an organosilicon fragment into the hydrocarbon chain connecting the phosphorus atoms in a diphosphine does not affect the properties of this compound as a modifier of cobalt carbonyl catalyst for olefin hydroformylation. The use of O-methyl-bis(dibutylphosphinoethyl)methylsilane as the modifier leads to the formation of an active and selective cobalt carbonyl catalyst for olefin hydroformylation.
Databáze: OpenAIRE