Co-ordination complexes containing multidentate ligands. Part 12. Nickel(II)–bismuth(III) co-ordination in nickel(II) complexes of tris(o-dimethylarsinophenyl)bismuthine and tris(3-dimethylarsinopropyl)bis-muthine

Autor:	Charles A. McAuliffe, Stephen G. Murray, William Levason
Rok vydání:	1977
Předmět:	Tris Bismuthine chemistry.chemical_compound Nickel Denticity Chelating ligands Chemistry Inorganic chemistry Polymer chemistry chemistry.chemical_element General Chemistry Bismuth
Zdroj:	J. Chem. Soc., Dalton Trans.. :711-714
ISSN:	1364-5447 0300-9246
Popis:	Two potentially quadridentate chelating ligands containing bismuth atoms have been synthesised: tris(o-dimethyl-arsinophenyl) bismuthine (L1) and tris(3-dimethylarsinopropyl)bismuthine (L2). Reaction of L1 with nickel(II) salts produces the essentially square-pyramidal [NiL1X]+(X = Cl, Br, or I) and [Ni2L13][ClO4]4 species, whilst L2 forms the trigonal-bipyramidal [NiL2(OH2)][ClO4]2. The resulting structures are discussed in terms of the structures of the ligands.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8cb628c2ce9b7ddd00a648fccc9dc228 https://doi.org/10.1039/dt9770000711 Zobrazit plný text záznamu