Catalytic performance of 11-molybdo-1-vanadophosphoric acid as a catalyst precursor and the optimization of reaction conditions for the oxidation of methane with hydrogen peroxide

Autor:	Makoto Misono, Yasuhiro Seki, Noritaka Mizuno
Rok vydání:	2000
Předmět:	chemistry.chemical_classification Reaction conditions Process Chemistry and Technology Inorganic chemistry Heterogeneous catalysis Trifluoroacetic acid anhydride Catalysis Methane chemistry.chemical_compound Hydrocarbon chemistry Hydrogen peroxide Oxygenate
Zdroj:	Applied Catalysis A: General. :13-20
ISSN:	0926-860X
DOI:	10.1016/s0926-860x(99)00348-8
Popis:	The oxidation of methane with hydrogen peroxide was carried out by using various Keggin-type heteropolyacids and V-containing complexes in trifluoroacetic acid anhydride. Among the catalysts tested, H4PV1Mo11O40 as a catalyst precursor catalyzed the selective oxidation into oxygenates most efficiently and showed high efficiency for the utilization of hydrogen peroxide. In addition, the reaction conditions were optimized.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8cb58817dc62894dae4bd087831f4f3f https://doi.org/10.1016/s0926-860x(99)00348-8 Zobrazit plný text záznamu Full Text from ScienceDirect