Synthesis of cyclic carbonates from CO2 and diols via electrogenerated cyanomethyl anion

Autor:	La-Xia Wu, Huan Wang, Ruina Li, Yongming Li, Aijian Zhang, Jian-Qing Zhao, Hisashi Kajiura, Jia-Xing Lu
Rok vydání:	2011
Předmět:	Reaction conditions Environmental Engineering Supporting electrolyte Diol Electrosynthesis Catalysis Ion chemistry.chemical_compound chemistry Cathode material Yield (chemistry) Polymer chemistry Environmental Chemistry Organic chemistry
Zdroj:	Greenhouse Gases: Science and Technology. 2:59-65
ISSN:	2152-3878
DOI:	10.1002/ghg.42
Popis:	The electrogenerated cyanomethyl anion reacts with diols in the presence of CO2 to yield the corresponding cyclic carbonates in moderated yields. The reported methodology has been carried out under mild conditions, avoiding any addition of classical bases, catalysts. In this communication, the effects of reaction conditions – such as supporting electrolyte, cathode material, current densities, charge amount, diol concentration – have been investigated to optimize the carbonates yield. © 2011 Society of Chemical Industry and John Wiley & Sons, Ltd
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8c88f7547e6c4d2f1da6af7a9a0477cc https://doi.org/10.1002/ghg.42 Zobrazit plný text záznamu Plný text