Polymerization of white phosphorus induced by internal β−-3H radiation

Autor:	Yu. V. Smetannikov, A. S. Vilesov, V. M. Byakov, V. P. Shevchenko, Natalia Tarasova
Rok vydání:	2008
Předmět:	Solvent chemistry.chemical_compound Inorganic polymer chemistry Polymerization White Phosphorus Phosphorus Inorganic chemistry chemistry.chemical_element Physical and Theoretical Chemistry Radiation Benzene
Zdroj:	Doklady Physical Chemistry. 423:335-338
ISSN:	1608-3121 0012-5016
Popis:	Available experimental and theoretical data demon-strate the ability of white phosphorus to form nanosizedassemblies in solutions [1]. Radiation-induced poly-merization of these assemblies leads to the formation ofan inorganic polymer (red phosphorus modified withsolvent fragments). The size distribution of the product,which determines to a great extent the useful propertiesof polymeric phosphorus, can be varied by changingthe conditions of this process (temperature, radiation,dose, solvent, additives) [2].We pioneered the polymerization of white phospho-rus in benzene and dioxane solutions containing tritiumwater (H
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8c6f4b1dc3b47ab495c1d4bd86ee3173 https://doi.org/10.1134/s0012501608120051 Zobrazit plný text záznamu Plný text ve formátu PDF