Ionic conductivity of conjugated water-soluble rigid-rod polymers
| Autor: | F. E. Arnold, D. P. Heberer, S. J. Bai, R. J. Spry, T. D. Dang |
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| Rok vydání: | 1993 |
| Předmět: |
chemistry.chemical_classification
Polymers and Plastics Dopant Chemistry Isotropy Chemical modification Polymer Conjugated system Condensed Matter Physics Chemical engineering Electrical resistivity and conductivity Liquid crystal Polymer chemistry Materials Chemistry Ionic conductivity Physical and Theoretical Chemistry |
| Zdroj: | Journal of Polymer Science Part B: Polymer Physics. 31:1941-1950 |
| ISSN: | 1099-0488 0887-6266 |
| DOI: | 10.1002/polb.1993.090311306 |
| Popis: | Poly[(1,7-dihydrobenzo [1,2-d:4,5-d'] diimidazole-2,6-diyl)-2-(2-sulfo) -p-phenylene], a conjugated rigid-rod polymer, was derivatized with pendants of propane-sulfonated ionomers. The derivatized rigid-rod polymer was soluble in aprotic solvents as well as in water for isotropic solutions that were processed into isotropic films. Room-temperature electrical conductivity σ as high as 2.9×10 -4 S/cm was achieved on pristine isotropic films without using dopants. When the rigid-rod polymer concentration exceeded 25 wt %, the isotropic solution could be transformed into a liquid-crystalline solution that allowed deformations to be applied to produce anisotropic films |
| Databáze: | OpenAIRE |
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