Reaction mechanism of CO methanation on nickel catalysts, as studied by isotopic and nonstationary methods

Autor:	N. A. Gaidai, Yu. A. Agafonov, A. L. Lapidus, Ho Si Thoang, Luu Cam Loc, N. V. Nekrasov, Nguyen Manh Huan
Rok vydání:	2011
Předmět:	inorganic chemicals Reaction mechanism Hydrogen Chemistry Inorganic chemistry chemistry.chemical_element General Chemistry Catalysis Computer Science Applications chemistry.chemical_compound Nickel Deuterium Methanation Modeling and Simulation Kinetic isotope effect Carbon monoxide
Zdroj:	Kinetics and Catalysis. 52:749-755
ISSN:	1608-3210 0023-1584
DOI:	10.1134/s0023158411050107
Popis:	Kinetic isotope effects were measured upon the replacement of hydrogen by deuterium in the reaction of carbon monoxide methanation on nickel catalysts supported on TiO2 and γ-Al2O3. Data on the mechanism of the process were obtained with the use of a nonstationary method. A step-scheme was proposed, in which the interaction of oxygen-containing compounds with hydrogen is a slow step of the process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8c48855cf37d24d484fc11e2dd86694a https://doi.org/10.1134/s0023158411050107 Zobrazit plný text záznamu Plný text ve formátu PDF