Fluorodienes. V. Copolymerization of 1,1,4,4-tetrafluoro-1,3-butadiene with oxygen and nitric oxide

Autor:	R. E. Putnam, W. H. Sharkey
Rok vydání:	1966
Předmět:	Diene technology industry and agriculture General Engineering 1 3-Butadiene chemistry.chemical_element macromolecular substances Photochemistry Oxygen Peroxide Nitric oxide chemistry.chemical_compound Monomer chemistry Polymerization Copolymer
Zdroj:	Journal of Polymer Science Part A-1: Polymer Chemistry. 4:2289-2293
ISSN:	1542-9350 0449-296X
DOI:	10.1002/pol.1966.150040922
Popis:	1,1,4,4-Tetrafluoro-1,3-butadiene reacts with oxygen to form a polyperoxide containing 1.0–1.1 peroxide groups for each diene unit. This polymer behaves like a typical peroxide. It explodes violently when heated to 120°C. or when subjected to shock, and it initiates polymerization of vinyl monomers at temperatures of 90°C. or higher. The tetrafluorobutadiene also copolymerizes with nitric oxide to give a highly crosslinked polymer containing three molecules of diene for each two molecules of nitric oxide.
Databáze:	OpenAIRE
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