Bisdithiolene complexes based on an extended ligand with TTF and pyridine moieties

Autor:	Manuel Almeida, Laura C. J. Pereira, I.C. Santos, Sandra Rabaça, R.T. Henriques, Sandra I. G. Dias
Rok vydání:	2012
Předmět:	chemistry.chemical_classification Ligand Salt (chemistry) Photochemistry Inorganic Chemistry chemistry.chemical_compound Paramagnetism Microcrystalline chemistry Pyridine Polymer chemistry Materials Chemistry Physical and Theoretical Chemistry Alkyl Tetrathiafulvalene
Zdroj:	Inorganic Chemistry Communications. 15:102-105
ISSN:	1387-7003
DOI:	10.1016/j.inoche.2011.10.001
Popis:	The synthesis and characterization of a new extended tetrathiafulvalene (TTF) dithiolene ligand substituted with alkyl pyridine groups, pyridylethylsulfanyltetrathiafulvalenedithiolene (pesdt2−), as well as the corresponding gold (III) complex [Au(pesdt)2]− obtained as a tetrabutylammonium salt are described. The oxidation potential of this complex is rather low and the paramagnetic neutral complex is obtained as an electrically insulating microcrystalline powder.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8c40133d06be48e6c2d0e360bcfe9fce https://doi.org/10.1016/j.inoche.2011.10.001 Zobrazit plný text záznamu Full Text from ScienceDirect