Optimization of thermospray conditions
| Autor: | Claes Lindberg, Jan Paulson |
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| Rok vydání: | 1987 |
| Předmět: | |
| Zdroj: | Journal of Chromatography A. 394:117-122 |
| ISSN: | 0021-9673 |
| DOI: | 10.1016/s0021-9673(01)94165-2 |
| Popis: | Vaporizer temperature and repeller potential were optimized for five test compounds analysed by liquid chromatography—thermospray mass spectrometry. Optimum values were about the same for most compounds. The MH + ion intensity of one thermally labile compound was maximal at a lower vaporizer temperature than those of the more stable compounds. The repeller potential affected the abundance of ammonium adduct ions relative to the MH + ions. The solvent-buffer ions could be used to optimize the vaporizer temperature but not the repeller potential for the test compounds. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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