A fluorescent and colorimetric chemosensor for Ga 3+ and CN –

Autor:	Cheal Kim, Jae Min Jung, Dongju Yun
Rok vydání:	2018
Předmět:	Inorganic Chemistry Nucleophilic addition Aqueous solution 010405 organic chemistry Chemistry Materials Chemistry Physical and Theoretical Chemistry 010402 general chemistry Photochemistry 01 natural sciences Fluorescence Fluorescence response 0104 chemical sciences
Zdroj:	Inorganica Chimica Acta. 479:154-160
ISSN:	0020-1693
DOI:	10.1016/j.ica.2018.04.021
Popis:	A novel chemosensor 1 based on 4-aminobenzophenone and 2-hydroxy-1-naphthaldehyde was synthesized for the recognition of Ga3+ and CN–. Chemosensor 1 displayed “turn-on” fluorescence response only to Ga3+, distinguishing from Al3+ and In3+, which have similar properties. Meanwhile, sensor 1 displayed color change of yellow to colorless by reacting with CN– via a nucleophilic addition process in aqueous solution. Sensor 1 was used to quantify CN– in real samples. Sensing processes of 1 toward Ga3+ and CN– were demonstrated by the various spectroscopic studies and theoretical calculations.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8c0209fdf2ead67bb4e92f88e00b0eb3 https://doi.org/10.1016/j.ica.2018.04.021 Zobrazit plný text záznamu Full Text from ScienceDirect