Methylation of phenol over Degussa P25 TiO2

Autor:	Julio B. Fernandes, Aditi R. Gandhe
Rok vydání:	2005
Předmět:	Reaction mechanism Process Chemistry and Technology Inorganic chemistry Cresol Heterogeneous catalysis Catalysis chemistry.chemical_compound chemistry medicine Phenol Phenols Methanol Physical and Theoretical Chemistry Selectivity medicine.drug
Zdroj:	Journal of Molecular Catalysis A: Chemical. 226:171-177
ISSN:	1381-1169
DOI:	10.1016/j.molcata.2004.10.035
Popis:	Degussa P25 TiO 2 was evaluated as a catalyst for vapour phase methylation of phenol. It gave an optimum conversion of 32% at 450 °C and formed predominantly the ortho -, para - and meta -cresols. The activity selectivity profiles are discussed in terms of the acid–base properties of the catalyst and the BET surface areas. A new mechanism is proposed to explain the observed product selectivity.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8be59544d2bf1fc55eef5f1d5c31fbf6 https://doi.org/10.1016/j.molcata.2004.10.035 Zobrazit plný text záznamu Full Text from ScienceDirect