Binuclear Osmium μ-Oxocarboxylate Complexes [Os2(μ-O)(μ-O2CR)2Cl4L2] (R = CH3, CCl3; L = PPh3, AsPh3) and Their Electrochemical Behavior in Dichloromethane

Autor:	A. V. Eremin, N. V. Evreinova, N. S. Panina, S. A. Simanova, A. I. Fisher, A. N. Belyaev
Rok vydání:	2004
Předmět:	General Chemical Engineering Inorganic chemistry chemistry.chemical_element General Chemistry Electronic structure Electrochemistry Redox Medicinal chemistry Coulometry chemistry.chemical_compound chemistry Osmium Carboxylate Cyclic voltammetry Dichloromethane
Zdroj:	Russian Journal of Coordination Chemistry. 30:296-299
ISSN:	1070-3284
DOI:	10.1023/b:ruco.0000022807.77697.ee
Popis:	Cyclic voltammetry and galvanostatic coulometry techniques were used to determine how the redox properties of osmium binuclear μ-oxocarboxylates [Os2 IV(μ-O)(μ-O2CR)2Cl4L2] (R = CH3, CCl3; L = PPh3 and R = CH3; L = AsPh3) are influenced by the nature of the bridging carboxylate ligand RCOO– and ligand L. It was shown that all compounds in solution of dichloromethane undergo two single-electron reduction processes. The data obtained were compared with the DFT calculations of the electronic structure of the model complexes [Os2 IV(μ-O)(μ-O2CR)2Cl4L′2] (R = CH3, CCl3; L′ = PH3 and R = CH3; L′ = AsH3).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8bdec023d565415c325ac6a55932ea02 https://doi.org/10.1023/b:ruco.0000022807.77697.ee Zobrazit plný text záznamu Full text from SpringerLink