Structural signs and carrier completeness of Liouvillian quasiparticle algebras: Dual group invariants for explicit ?n-auxiliary tensor labels via projective mappings applicable to [A]n?20 NMR spin ensembles

Autor: F. P. Temme
Rok vydání: 2002
Předmět:
Zdroj: International Journal of Quantum Chemistry. 89:429-440
ISSN: 1097-461X
0020-7608
DOI: 10.1002/qua.10311
Popis: Various structural sign aspects of (Liouvillian) dual carrier spaces are examined under (quasiparticle [QP]) dual group projective mappings and Lie-based algebras. The completeness of these superboson mappings and the nature of the correlation between the two distinct spatial QP sets of mappings are demonstrated in a direct Lie algebraic approach as being superior to supergenerator-based right-derivation methods. The dual tensorial auxiliary labels of superboson dual carrier mappings are presented in terms of dual group invariants based on democratic recoupling. The 2n decompositional modeling is utilized for the cardinality of SU(2) × 2n group invariants (SIs) of (polyhedral) higher-(2n) [A]2n: 12 ∼ 2n ≤ 20 systems and the auxiliary “v” sets. Use of (augmented Weyl) time-reversal invariance over sets of uniform (democratic) (2n)-apical geometric lattice points allows one to treat all the intrinsic (2i) < (2n) subproblems originating from stepwise substitution of (I · I) pairs by 1 unities. Use of established 2n logic provides a ∑ (χ)2(n) model for the fundamental |SI| terms. PACS: 2.10; 02.20-a; 33.20 Vq; 33.25 + j. © 2002 Wiley Periodicals, Inc. Int J Quantum Chem, 2002
Databáze: OpenAIRE