Sonolysis and radiolysis of glyceraldehyde in deaerated aqueous solution
| Autor: | Eva Fuchs, H. Heusinger |
|---|---|
| Rok vydání: | 1995 |
| Předmět: |
chemistry.chemical_classification
Reaction mechanism Aqueous solution Acoustics and Ultrasonics Dimer Radical Organic Chemistry Photochemistry Aldehyde Sonochemistry Inorganic Chemistry chemistry.chemical_compound chemistry Glyceraldehyde Radiolysis Chemical Engineering (miscellaneous) Environmental Chemistry Radiology Nuclear Medicine and imaging |
| Zdroj: | Ultrasonics Sonochemistry. 2:S105-S109 |
| ISSN: | 1350-4177 |
| DOI: | 10.1016/1350-4177(94)00014-j |
| Popis: | The objective of this work was to contribute to the mechanism of the sonolytic and radiolytic reactions leading in deaerated aqueous solutions of sugars to products by radical-radical combination. For this purpose glyceraldehyde, the first homologue of the series of aldoses, was investigated. Primary glyceraldehyde radicals are produced by abstraction of carbon-bonded hydrogen atoms by sonolytic or radiolytic H and OH radicals. Secondary glyceraldehyde radicals are derived from primary radicals by elimination of water. Both kinds of radicals were found to participate in dimer production. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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