Catalytic splitting of acetals to unsaturated ethers
| Autor: | Libor Cerveny, P. Winklerova, Antonín Marhoul |
|---|---|
| Rok vydání: | 2007 |
| Předmět: |
chemistry.chemical_classification
Renewable Energy Sustainability and the Environment General Chemical Engineering Organic Chemistry Kinetics Acetal Ether Pollution Aldehyde Catalysis Heptanal Inorganic Chemistry Acid catalysis chemistry.chemical_compound Fuel Technology chemistry Organic chemistry Selectivity Waste Management and Disposal Biotechnology |
| Zdroj: | Journal of Chemical Technology & Biotechnology. 58:211-214 |
| ISSN: | 1097-4660 0268-2575 |
| Popis: | Catalytic splitting of the dimethylacetals of heptanal, 3-cyclohexyl-propanal, 3-cyclohexylbutanal, 3-phenylpropanal and 3-phenylbutanal to corresponding unsaturated ethers was studied in a gas phase. Acid catalysts were employed in the study. Reaction conditions favorable to high splitting selectivity to ethers were suggested. The original acetals as well as synthesized unsaturated methylethers revealed characteristic odoring properties |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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