Biological treatment of wastewater with high concentrations of zinc and sulfate ions from zinc pyrithione synthesis

Autor: Xiang Haihong, Michal Green, Sheldon Tarre, Hui-jun He, Guangming Zeng, Yan Cheng, Yan Zhou, Peng Zhixiong, Wen Shan, Chunping Yang
Rok vydání: 2017
Předmět:
Zdroj: Transactions of Nonferrous Metals Society of China. 27:2481-2491
ISSN: 1003-6326
Popis: An enriched and domesticated bacteria consortium of sulfate-reducing bacteria (SRB) was used to treat wastewater from zinc pyrithione (ZPT) production, and the effects of different reaction parameters on sulfate reduction and zinc precipitation were evaluated. The single-factor experimental results showed that the removal rates of Zn2+ and SO42− decreased with an increased ZPT concentration ranging from 3.0 to 5.0 mg/L. Zn2+ and SO42− in wastewater were effectively removed under the conditions of 30–35 °C, pH 7–8 and an inoculum concentration of 10%–25%. The presence of Fe0 in the SRB system enhanced Zn2+ and SO42− removal and may increase the resistance of SRB to the toxicity of Zn2+ and ZPT in wastewater. A Box–Behnken design was used to evaluate the influence of the main operating parameters on the removal rate of SO42−. The optimum parameter values were found to be pH 7.45, 33.61 °C and ZPT concentration of 0.62 mg/L, and the removal rate of SO42− reached a maximum of 91.62% under these optimum conditions.
Databáze: OpenAIRE