An impurity band in Hg3In2Te6 crystals doped with silicon

Autor: O. G. Grushka, P. N. Gorlei
Rok vydání: 2003
Předmět:
Zdroj: Semiconductors. 37:168-171
ISSN: 1090-6479
1063-7826
DOI: 10.1134/1.1548659
Popis: The influence of silicon impurity on the energy-band spectrum in the Hg3In2Te6 semiconductor compound, which incorporated a high concentration of stoichiometric vacancies, was studied on the basis of the results of electrical and optical measurements. It is shown that silicon impurity forms an impurity band of donor states whose density can be approximated by a Gaussian distribution with a peak at Ec-0.29 eV. The emergence of the impurity band is accompanied with the formation of a quasi-continuous spectrum of localized states in the band gap (Eg=0.74 eV); the density of these states is shown to increase as the doping level increases. All states merge into a continuous band if the impurity concentration NSi>4.5×1017 cm−3. Experimental data are explained on the basis of the effect of impurity self-compensation, in which case donor impurity states arise simultaneously with acceptor states of defects.
Databáze: OpenAIRE