SYNTHESIS AND CHARACTERIZATION OF L=4-(2-AMINOPHENYLIMINO)-PENTEN-2-OL. AND ITS COMPLEXES [ML(H2O)] ; M= Zn(II), Cd(II), Ni(II), Cu(II) AND Co(II)
| Autor: | EL. Amane, M., Kennouche, Y., EL Hamdani, H., Bouhdada, M., Chihab, M. |
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| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: | |
| DOI: | 10.48369/imist.prsm/jmch-v17i2.13181 |
| Popis: | 4-(2-amino-phenylimino)-pentene-2-ol (L) was obtained by condensation of acetylacetone and o-phenylenediamine in ethanolic medium. The reactions stoichiometries between the metal(II) ion and the ligand (L) in molar ratio of M:L (1:1) resulted in the formation of the complexes of types [ML(H2O)]. The ligand (L) and its complexes have been characterized with the help of melting point, molar conductance, electronic and infrared spectra. From the data, it is found that all the complexes of formula [ML(H2O)] ; M= Zn(II), Cd(II), Ni(II), Cu(II) and Co(II) posses tetragonal geometry. Moroccan Journal of Heterocyclic Chemistry, Vol 17, No 2 (2018) |
| Databáze: | OpenAIRE |
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