Synthesis and Estimation of Radical Scavenging Activity of Tetra(meso-aryl)porphyrins Containing 2,6-Dimethoxyphenol Unit
| Autor: | Dmitry V. Belykh, N. I. Sheludchenko, T. K. Rocheva, L. I. Mazaletskaya |
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| Rok vydání: | 2018 |
| Předmět: |
biology
010405 organic chemistry Aryl Hydroxy group Azobisisobutyronitrile General Chemistry 010402 general chemistry biology.organism_classification 01 natural sciences Medicinal chemistry Ethylbenzene 0104 chemical sciences chemistry.chemical_compound chemistry polycyclic compounds Phenol Tetra Scavenging |
| Zdroj: | Russian Journal of General Chemistry. 88:1635-1640 |
| ISSN: | 1608-3350 1070-3632 |
| DOI: | 10.1134/s1070363218080145 |
| Popis: | Tetra(meso-aryl)porphyrins containing 2,6-dimethoxyphenol unit distant from the macrocycle and adjacent to it have been prepared. Radical scavenging activity of the obtained compounds has been estimated in the model reaction of ethylbenzene oxidation initiated by azobisisobutyronitrile. It has been shown that the phenol hydroxy group ability to inhibit ethylbenzene oxidation depends on the environment of phenol group. |
| Databáze: | OpenAIRE |
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