Study of the polymerization of solid vinyl monomers using differential scanning calorimetry
| Autor: | Maher Z. Elsabee, Ahmed A.M. Ali, Fakhreia Al-Sagheer |
|---|---|
| Rok vydání: | 1999 |
| Předmět: |
Kinetic chain length
Materials science Polymers and Plastics Bulk polymerization Organic Chemistry Radical polymerization technology industry and agriculture Cationic polymerization Chain transfer macromolecular substances Chain-growth polymerization Polymer chemistry Reversible addition−fragmentation chain-transfer polymerization Ionic polymerization |
| Zdroj: | Polymer Testing. 18:313-319 |
| ISSN: | 0142-9418 |
| DOI: | 10.1016/s0142-9418(98)00034-8 |
| Popis: | Two vinyl monomers with a heterocyclic group have been prepared. The solid state polymerization of the two monomers was investigated by DSC. The activation energy as well as the order of reaction were calculated using different free radical initiators. It has been shown that the nature of the monomer and the initiator affect the behavior of polymerization. 1H NMR spectroscopy was used to confirm the polymerization. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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