ChemInform Abstract: Palladium(II)-Catalyzed Transfer Vinylation of Protected Monosaccharides

Autor:	Marcel Schlaf, Sean Handerson
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Anomer Ligand Chemistry organic chemicals chemistry.chemical_element General Medicine Decomposition Catalysis Solvent Yield (chemistry) Polymer chemistry Organic chemistry Monosaccharide Palladium
Zdroj:	ChemInform. 33
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200226193
Popis:	A method for the catalytic vinylation of protected monosaccharides bearing a single free hydroxyl function has been developed. Reaction of representative primary, secondary, and anomeric sugar hydroxyl functions with butyl vinyl ether as the reactant and solvent and (phen)Pd(OAc)2 (phen = 1,10-phenanthroline ligand) as the catalyst gives the corresponding vinylated sugar products in 36−79% yield. The catalyst requires the presence of traces of oxygen in the reaction mixture to prevent decomposition to Pd(0).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8b54c62bcba6791aba81a13fca1d628a https://doi.org/10.1002/chin.200226193 Zobrazit plný text záznamu Plný text