Dynamic Reorganization and Confinement of TiIV Active Sites Controls Olefin Epoxidation Catalysis on Two-Dimensional Zeotypes
Autor: | Stacey I. Zones, Nicolás A. Grosso-Giordano, Simon R. Bare, Alexey Boubnov, Alexander Katz, David W. Small, Adam S. Hoffman |
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Rok vydání: | 2019 |
Předmět: | |
Zdroj: | Journal of the American Chemical Society. 141:7090-7106 |
ISSN: | 1520-5126 0002-7863 |
DOI: | 10.1021/jacs.9b02160 |
Popis: | The effect of dynamic reorganization and confinement of isolated TiIV catalytic centers supported on silicates is investigated for olefin epoxidation. Active sites consist of grafted single-site ca... |
Databáze: | OpenAIRE |
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