Dynamic Reorganization and Confinement of TiIV Active Sites Controls Olefin Epoxidation Catalysis on Two-Dimensional Zeotypes

Autor: Stacey I. Zones, Nicolás A. Grosso-Giordano, Simon R. Bare, Alexey Boubnov, Alexander Katz, David W. Small, Adam S. Hoffman
Rok vydání: 2019
Předmět:
Zdroj: Journal of the American Chemical Society. 141:7090-7106
ISSN: 1520-5126
0002-7863
DOI: 10.1021/jacs.9b02160
Popis: The effect of dynamic reorganization and confinement of isolated TiIV catalytic centers supported on silicates is investigated for olefin epoxidation. Active sites consist of grafted single-site ca...
Databáze: OpenAIRE