Simple synthesis of platinum–palladium nanoflowers on reduced graphene oxide and their enhanced catalytic activity for oxygen reduction reaction
Autor: | Jie-Ning Zheng, Meng Lin, Hong-Bao Zhang, Jing-Jing Lv, Ai-Jun Wang, Jianrong Chen, Jiu-Ju Feng |
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Rok vydání: | 2014 |
Předmět: |
Renewable Energy
Sustainability and the Environment Reducing agent Chemistry Graphene Inorganic chemistry Hydrazine Oxide Energy Engineering and Power Technology chemistry.chemical_element Electrocatalyst law.invention Catalysis chemistry.chemical_compound Chemical engineering law Electrical and Electronic Engineering Physical and Theoretical Chemistry Platinum Palladium |
Zdroj: | Journal of Power Sources. 269:136-143 |
ISSN: | 0378-7753 |
DOI: | 10.1016/j.jpowsour.2014.06.149 |
Popis: | A simple and rapid one-pot wet-chemical method is developed for large-scale preparation of reduced graphene oxide nanosheets supporting Pt–Pd nanoflowers (Pt–Pd NFs/RGOs) using hydrazine hydrate as a reducing agent, without any seed, template, organic solvent, or special apparatus. The coexistence of sodium nitrite (NaNO 2 ) and poly(vinyl pyrrolidone) (PVP), and their amounts are essential for synthesis of flower-like nanostructures. Besides, Pt–Pd NFs/RGOs have higher catalytic activity and better durability for oxygen reduction reaction, compared with commercial Pt–C (50 wt %). |
Databáze: | OpenAIRE |
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