Studies on the proton acceptor ability of phosphoryl compounds

Autor:	V. V. Prezhdo, E.V. Vaschenko, Oleg V. Prezhdo
Rok vydání:	1996
Předmět:	Kerr constant Stereochemistry Polarity (physics) Organic Chemistry Complex formation Analytical Chemistry Inorganic Chemistry Dipole chemistry.chemical_compound Crystallography chemistry Polarizability Phenols Proton acceptor Spectroscopy
Zdroj:	Journal of Molecular Structure. 385:137-144
ISSN:	0022-2860
DOI:	10.1016/s0022-2860(96)09402-1
Popis:	Dipole moments and molar Kerr constants of complexes of phenols with phosphoryl compounds were studied to establish the structure of complexes and parameters characterizing the proton acceptor ability of these compounds. The structures of these complexes and parameters ( μ H , Δ ( mk ) S , log K and δ 0 ) were established. It has been suggested that a new parameter Δ ( mK ) S — structural additive difference of the molar Kerr constant — makes it possible to determine changes of polarity and polarizability of the systems during complex formation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8b33de011aba23a8dd6909b23a3e8471 https://doi.org/10.1016/s0022-2860(96)09402-1 Zobrazit plný text záznamu Full Text from ScienceDirect