ChemInform Abstract: On the Use of Removable Steric Buttresses in Cycloaddition Reactions
| Autor: | Anjum Dadabhoy, Peter G. Sammes, Nandeo Choony |
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| Rok vydání: | 2010 |
| Předmět: | |
| Zdroj: | ChemInform. 29 |
| ISSN: | 1522-2667 0931-7597 |
| DOI: | 10.1002/chin.199849057 |
| Popis: | Use of bulky protecting groups, such as the trityl group, can be utilised to encourage cycloaddition reactions that otherwise do not proceed. Thus N-allylfurfurylamines, bearing the appropriate N-protecting group, can thermally cyclise; subsequent removal of the protecting group produces the thermodynamically unstable, free amine. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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