Energy level analysis of Np3+:LaCl3 and Np3+:LaBr3
| Autor: | H. M. Crosswhite, R. Sarup, Norman M. Edelstein, W. T. Carnall, George V. Shalimoff, John G. Conway, Jan P. Hessler |
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| Rok vydání: | 1980 |
| Předmět: | |
| Zdroj: | The Journal of Chemical Physics. 72:5089-5102 |
| ISSN: | 1089-7690 0021-9606 |
| DOI: | 10.1063/1.439797 |
| Popis: | The polarized absorption and fluorescence spectra of 0.01–5% Np3+ doped into single‐crystal LaCl3 were measured at moderate and high resolution in the range to 50 000 cm−1 at 298, 77, and 4 K. The 150 crystal field components identified were fit by a parametrized model which has previously been shown to provide an excellent account of the energy level structures observed for lanthanides doped into LaCl3. This constitutes the first successful evaluation of the crystal field interaction for an actinide ion in LaCl3 in which J mixing effects were explicitly included. The crystal field parameters for Np3+:LaCl3, B20=163, B40=−632, B60=−1625, and B66=1028, all in cm−1, were determined to be approximately twice as large as those for the analogous lanthanide, Pm3+:LaCl3. From analysis of Zeeman patterns in the fluorescence spectra, the ground state was found to be doubly degenerate, having crystal quantum numbers ±2 and a parallel splitting factor 0.17 LU (Lorentz unit). |
| Databáze: | OpenAIRE |
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