Separation of Rare Earth Elements (REE) by Ion Interaction Chromatography (IIC) Using Diglycolic Acid (ODA) as a Complexing Agent
| Autor: | Krzysztof Kulisa, Rajmund Dybczyński |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Lanthanide
Chromatography Ion exchange Elution 010401 analytical chemistry Organic Chemistry Clinical Biochemistry Diglycolic acid chemistry.chemical_element Yttrium 010501 environmental sciences 01 natural sciences Biochemistry 0104 chemical sciences Analytical Chemistry Ion chemistry.chemical_compound chemistry Atomic number Scandium 0105 earth and related environmental sciences |
| Zdroj: | Chromatographia. 84:473-482 |
| ISSN: | 1612-1112 0009-5893 |
| DOI: | 10.1007/s10337-021-04025-y |
| Popis: | The possibility of rare earth elements (REE) separation by ion interaction chromatography (IIC) employing their complexes with diglycolic acid (ODA) in anion exchange mode has been studied theoretically and experimentally. Calculations, assuming that only trivalent complex is significantly uptaken by the stationary phase, indicated that at at pH 4–6, the retention in the lanthanide series should increase from La to the Tb–Dy–Ho region with yttrium showing apparent atomic number (App.At.No.) of 67½ and then decrease with further increase of atomic number. Chromatographic experiments in the system: Column: Eternity C18—mobile phase 5 mM ODA/8.6 mM TBAOH/0.6 mM HNO3; pH 4.60 confirmed theoretically predictions. It was found that scandium at pH ≥ 4.0 elutes in front of the whole REE group but at low pH enters the region of light lanthanides. The non-monotonical change of affinity of the REE with the increase of atomic number results in quite unusual order of elution of REE namely: Sc |
| Databáze: | OpenAIRE |
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