Comparative studies on data collection and data treatment in kinetic-based determination with two rotating bioreactor / amperometric detection systems

Autor: Kiyoshi. Matsumoto, Horacio A. Mottola, J. J. Baeza Baeza
Rok vydání: 1993
Předmět:
Zdroj: Analytica Chimica Acta. 283:785-793
ISSN: 0003-2670
DOI: 10.1016/0003-2670(93)85293-s
Popis: Twol cell configurations involving a rotating bioreactor and a stationary platinum-ring amperometric detector are compared with regard to data produced by continuous-flow and continuous-flow/stopped-flow/continuous-flow operations. In addition to data collection, six kinetic-based approaches to data treatment are also compared. The approaches to data treatment considered here are: (1) the initial rate measurement, (2) integration of the signal time profile, (3) a linear steady-state predictive approach, (4) a nonlinear steady-state predictive approach, (5) a single measurement fixed-time mode, and (6) a multimeasurement fixed-time mode.
Databáze: OpenAIRE