Products of the electrochemical reduction of borylphosphinoethene in a nonaqueous medium

Autor:	O. A. Erastov, Anna S. Balueva, G. A. Vagina, T. V. Troepol'skaya
Rok vydání:	1991
Předmět:	chemistry.chemical_classification Reduction (complexity) chemistry.chemical_compound Electrolysis chemistry Sulfide law Selenide Inorganic chemistry Oxide General Chemistry Electrochemistry law.invention
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 40:165-168
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00959651
Popis:	In order to confirm our earlier assumptions with respect to the processes involved in the electrochemical reduction of borylphosphinoethene derivatives, we have analyzed the products of controlled-potential electrolysis. Compounds were isolated and identified, formed in the further chemical conversions of the initially formed unstable intermediates. It has been demonstrated that the electroreduction of the borylphosphinoethene oxide in an aprotic medium leads primarily to splitting of the P-CAr bond and in the case of the borylphosphinoethene selenide to the reduction of the P=Se bond; in the reduction of the corresponding sulfide both these fragments are affected.
Databáze:	OpenAIRE
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