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In the recent years, the global energy economy is experiencing a transition towards its production from more sustainable and “green” sources. The intrinsic characteristics of these methods, such as the intermittency and misalignment between disposability and demand, require the use of energy storage systems, such as secondary batteries. Despite the high performance of Li-ion batteries, the high cost, low abundance and toxicity of their components (e.g., the Co-based cathodes) request the development of new devices based on novel chemistries. In this regard, the holy grail is the production of battery systems based on abundant multivalent metals. It has been recently demonstrated that ionic liquids (ILs) are suitable solvents in order to obtain stable and high performing electrolytes able to conduct and deposit/strip multivalent metals [1-5]. The outstanding electrochemical properties of these materials are ensured by the presence of a high-reactive magnesium salt (i.e., the “delta” form of MgCl2) and of a suitable metal halide (e.g., AlCl3, TiCl4, etc.). In this project we have developed a family of IL-based electrolytes for the Mg2+ ion conduction doped with an alkyl tin halide compound. In this way, the hybrid chemico-physical properties of Sn-based species can be exploited to improve the coordination existing between the inorganic magnesium salt and the organic IL. An advanced study on the thermal and structural properties of the proposed material will be presented, with a particular focus on the interactions established between the different chemical species and complexes composing the materials. Insights on the conductivity mechanism occurring in a wide range of temperature will be gauged and thoroughly described by means of the broadband electrical spectroscopy studies. Acknowledgments The project “Interplay between structure, properties, relaxations and conductivity mechanism in new electrolytes for secondary Magnesium batteries” (Grant Agreement W911NF-21-1-0347-(78622-CH-INT)) of the U.S. Army Research Office. The project “ACHILLES” (prot. BIRD219831) of the University of Padua. The project “VIDICAT” (Grant Agreement 829145) of the FET-Open call of Horizion 2020. References [1] G. Pagot, K. Vezzù, S. Greenbaum and V. Di Noto, Journal of Power Sources 492 (2021) 229681. [2] R. Dominko, J. Bitenc, R. Berthelot, M. Gauthier, G. Pagot and V. Di Noto, Journal of Power Sources 478 (2020) 229027. [3] G. Pagot, F. Bertasi, K. Vezzù, F. Sepehr, X. Luo, G. Nawn, E. Negro, S.J. Paddison and V. Di Noto, Electrochimica Acta 246 (2017) 914-923. [4] F. Bertasi, F. Sepehr, G. Pagot, S.J. Paddison and V. Di Noto, Advanced Functional Materials 26 (2016) 4860-4865. [5] F. Bertasi, C. Hettige, F. Sepehr, X. Bogle, G. Pagot, K. Vezzù, E. Negro, S.J. Paddison, S.G. Greenbaum, M. Vittadello and V. Di Noto, ChemSusChem 8 (2015) 3069-3076. |
