Electronic absorption spectrum and π-electronic structure of cryptocyanine

Autor:	A. Novak, Viktor Řehák, M. Titz
Rok vydání:	1980
Předmět:	Absorption spectroscopy Chemistry General Chemistry Electronic structure Atomic physics
Zdroj:	Collection of Czechoslovak Chemical Communications. 45:307-320
ISSN:	1212-6950 0010-0765
DOI:	10.1135/cccc19800307
Popis:	Absorption, fluorescence excitation and APF spectra of cryptocyanine have been measured. Dipole moment of the respective S1 excited state has been estimated from shifts of the marked maximum of the first absorption band in various solvents. On the basis of quantum-chemical calculations carried out by the PPP method in the approximation of quasi-real geometry we have received the optimum model of π-electronic structure of the cryptocyanine molecule and therefrom the theoretical electronic singlet spectrum inclusive character of the S0 - S1 transition.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8ac87b2574df6b60da8f7c704ac56f1b https://doi.org/10.1135/cccc19800307 Zobrazit plný text záznamu