Aminium-Radical-Mediated Intermolecular Hydroamination of Nonactivated Olefins

Autor: Fei Wang, Si-Ming Jia, Yi-Hang Huang
Rok vydání: 2022
Předmět:
Zdroj: Synlett. 34:93-100
ISSN: 1437-2096
0936-5214
DOI: 10.1055/s-0042-1751390
Popis: Aminium radicals are attractive intermediates in synthetic chemistry that readily participate in a series of C–N bond-forming processes. Here, we briefly discuss strategies for generating aminium radicals from various precursors in the context of intermolecular alkene amination, and we highlight recent advances in aminium-radical-mediated hydroaminations of nonactivated olefins to directly approach alkylamines.1 Introduction2 Intermolecular Hydroamination of Nonactivated Alkenes with Alkylamines under Photoredox Catalysis3 Intermolecular Hydroamination of Nonactivated Alkenes with Aliphatic Azides4 Conclusions
Databáze: OpenAIRE