PHOSPHORYLATION OF 5-ARYLMETYLIDENE-1-MORPHOLINOCYCLOPENTENES
| Autor: | Aleksandr M. Pinchuk, Anatoly P. Marchenko, Nikolai v. Lysenko, Aleksandr N. Kostyuk, Andrei A. Tolmachev, Georgy N. Koidan |
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| Rok vydání: | 1998 |
| Předmět: |
inorganic chemicals
Chemistry Phosphorus Organic Chemistry Halide chemistry.chemical_element macromolecular substances environment and public health Biochemistry Medicinal chemistry Decomposition Inorganic Chemistry enzymes and coenzymes (carbohydrates) Hydrolysis bacteria Organic chemistry Phosphorylation |
| Zdroj: | Phosphorus, Sulfur, and Silicon and the Related Elements. 139:209-229 |
| ISSN: | 1563-5325 1042-6507 |
| DOI: | 10.1080/10426509808035689 |
| Popis: | The phosphorylation reaction of 5–arylmethylidene–1–morpholinocyclopentenes with various phosphorus (III) and (V) halides was studied. It was shown that the enamines react with phosphorus (III) halides giving stable halo– and dihalophosphines which are key substances for further synthesis. Hydrolysis of the phosphorylated enamines does not afford the expected phosphorylated ketones, decomposition being observed in acidic media. |
| Databáze: | OpenAIRE |
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