Crystal structure and properties of the 7,7,8,8-tetracyano-p-quinodimethanide salt of the 1,1′-bis-(p-cyanophenyl)-4,4′-bipyridinium dication

Autor:	Graham H. Cross, Deirdre A. Kennedy, Ian W. Nowell, J. Graham Allen, Geoffrey J. Ashwell
Rok vydání:	1983
Předmět:	Crystallography chemistry.chemical_compound Nitrile Chemistry Electrical resistivity and conductivity Stereochemistry X-ray crystallography Stacking Molecule Crystal structure Triclinic crystal system Dication
Zdroj:	J. Chem. Soc., Perkin Trans. 2. :1787-1791
ISSN:	1364-5471 0300-9580
DOI:	10.1039/p29830001787
Popis:	The crystal structure of [1,1′-bis-(p-cyanophenyl)-4,4′-bipyridinium]2+(7,7,8,8-tetracyano-p-quinodi-methanide)42–, CPP–TCNQ4, its electrical conductivity, and the properties of the TCNQ salts of five para-substituted dications are reported. CPP–TCNQ4 is triclinic, space group P, with a= 7.558(5), b= 13.501(4), c= 15.155(4)A, α= 102.8(2), β= 100.60(4), γ= 98.43(4)°, U= 1 458.5 A3, Dm= 1.36 Mg m–3, Z= 1, Dc= 1.34 Mg m–3. The structure was solved by direct methods and refined to a final R of 0.048 for 2 338 observed reflections. The radical anions stack, plane-to-plane, in columns parallel to b, the mean inter-TCNQ spacings being 3.28, 3.36, and 3.00 A between TCNQ(A)–TCNQ(A′), TCNQ(A)–TCNQ(B), and TCNQ(B)–TCNQ(B′), respectively. Adjacent columns form sheets, parallel to (001), successive sheets being interleaved along c by the CPP dications. The electrical conductivity along b, the direction of stacking, varies as σ=σ0exp(–Ea/kT) where σ300 K 0.1 S cm–1 and Ea 0.10 eV.
Databáze:	OpenAIRE
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