2,6-di-tert-butyl-4-perimidylphenols and their oxidation

Autor:	V. Kh. Sabanov, T. I. Chulkova, O. Yu. Okhlobystin, E. S. Klimov, F. Kim
Rok vydání:	1992
Předmět:	Tert butyl Chemistry Sodium pyrosulfate Inorganic chemistry Lead dioxide General Chemistry Toluene law.invention chemistry.chemical_compound law Oxidizing agent Polymer chemistry Phenol Electron paramagnetic resonance
Zdroj:	Theoretical and Experimental Chemistry. 28:58-60
ISSN:	1573-935X 0040-5760
Popis:	1,8-Naphthylenediamine was reacted with 2,6-di-tert-butyl-4-formyl-phenol to produce 2,6-di-tert-butyl-4-(1,3-dihydro-perimidyl) phenol (I). The latter was coverted into 2,6-di-tert-butyl-4-(1H-perimidyl)phenol (II) by oxidizing I with sodium pyrosulfate. When phenol II was oxidized by lead dioxide in toluene and THF, the EPR spectra revealed a 12-component multiplet with perimidyl splitting constants a1N=a3N=aHNH=0.2 mT; aH6.7=0.6 mT.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8a86d9f9976cafce9e4cdc0dc5c1be3a https://doi.org/10.1007/bf01006997 Zobrazit plný text záznamu Full text from SpringerLink