Dipole moments and enthalpies of complex formation of trimethyl-, triethyl-, and triphenylaluminum with n-donors

Autor:	E. N. Gur'yanova, Zh. S. Galuashvili, N. N. Korneev, K. A. Kocheshkov, I. P. Romm
Rok vydání:	1975
Předmět:	chemistry.chemical_classification Dipole chemistry.chemical_compound chemistry Sulfide Polarity (physics) Computational chemistry Complex formation Enthalpy Ether General Chemistry Medicinal chemistry
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 24:2598-2602
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf01152855
Popis:	1. Dipole moments and heat effects of formation reactions of complexes of trimethyl-, triethyl-, and triphenylaluminum with amines, ethers, and sulfides of various structure were measured. 2. Polarity and stability of donor-acceptor bonds of complexes of trimethyl- and tri-ethylaluminum with the corresponding n-donors are similar to and slightly lower than the polarity and stability of triphenylaluminum complexes. 3. The dimerization energy of triphenylaluminum was evaluated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8a7cb4bc075bfaa3f98fff650cc6e3a0 https://doi.org/10.1007/bf01152855 Zobrazit plný text záznamu Full text from SpringerLink