Asymmetric Carbonyl Migration of α-Amino Acid Derivatives via Memory of Chirality

Autor:	Fumiteru Teraoka, Tomoyuki Yoshimura, Kaoru Fuji, Orhan Ozturk, Takeo Kawabata
Rok vydání:	2011
Předmět:	chemistry.chemical_classification Ketone Chemistry Stereochemistry Organic Chemistry Enantioselective synthesis Stereoselectivity Enantiomeric excess Chirality (chemistry) Amino acid
Zdroj:	Synlett. 2011:543-546
ISSN:	1437-2096 0936-5214
Popis:	N-tert-Butoxycarbonylcarbamates of α-amino acid derivatives underwent asymmetric carbonyl migration by treatment with KHMDS in DMF to give α-amino acid derivatives with an additional ester group at the newly formed tetrasubstituted carbon center in up to 99% ee.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8a798b13e5680b1ae737d7e4f289f3ff https://doi.org/10.1055/s-0030-1259324 Zobrazit plný text záznamu