The Pathway of the Reaction between [(Me3Si)2N]2S and SeCl4
| Autor: | Petri Ingman, Arto Maaninen, Markku Ahlgrén, Risto S. Laitinen |
|---|---|
| Rok vydání: | 2001 |
| Předmět: |
Inorganic Chemistry
Deuterium NMR Crystallography Chemistry NMR spectroscopy of stereoisomers Carbon-13 NMR satellite Organic Chemistry Phosphorus-31 NMR spectroscopy Transverse relaxation-optimized spectroscopy Nuclear magnetic resonance spectroscopy Nuclear magnetic resonance crystallography Fluorine-19 NMR Biochemistry |
| Zdroj: | Phosphorus, Sulfur, and Silicon and the Related Elements. 169:161-164 |
| ISSN: | 1563-5325 1042-6507 |
| DOI: | 10.1080/10426500108546615 |
| Popis: | The reaction of [(Me3Si)2N]2S with an equimolar amount of SeCl4 in CS2 or CH2Cl2 at –70°C provides a route to 1,5-Se2S2N4 in a good yield. When the reaction is carried out in dioxane at +50°C five membered heterocycle (SSe2N2Cl)2 is formed. The product is identified and characterized using X-Ray diffraction, Raman spectroscopy, mass spectroscopy and NMR spectroscopy. 77Se MAS NMR study of the 1,5-Se2S2N4 is reported. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|