NOx− anion recognition by bimetallic cryptates: selectivity for nitrite over nitrate

Autor:	Shourya Gupta, Anju B S, Subrata Kundu, Taraknath Chattopadhyay, Jeffery A. Bertke, S. Ananya
Rok vydání:	2019
Předmět:	010405 organic chemistry Inorganic chemistry Nitrate anion 010402 general chemistry 01 natural sciences 0104 chemical sciences Ion Inorganic Chemistry Metal chemistry.chemical_compound Nitrate chemistry visual_art visual_art.visual_art_medium Nitrite Selectivity Bimetallic strip NOx
Zdroj:	Dalton Transactions. 48:7085-7089
ISSN:	1477-9234 1477-9226
DOI:	10.1039/c8dt04971h
Popis:	Nitrate and nitrite anions have multifaceted impacts on the environment and human health. We herein report selective recognition of nitrite over nitrate anion inside the cavity of bimetallic azacryptates having p-xylyl spacers. This work reveals a number of binding interactions which play pivotal roles in nitrite anion recognition by rigid metal cryptates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::8a72c109d8cdb010b4a7d93cfc1d4576 https://doi.org/10.1039/c8dt04971h Zobrazit plný text záznamu