Effect of temperature on the structure and electronic properties of the liquid alloy K–Sb
| Autor: | Roland Winter, R. Kurzhöfer, K. Hochgesand, Chr. Biermann |
|---|---|
| Rok vydání: | 1999 |
| Předmět: |
Chemistry
Structure (category theory) Mineralogy Thermodynamics Reverse Monte Carlo Neutron scattering Conductivity Liquid alloy Condensed Matter Physics Electronic Optical and Magnetic Materials Electrical resistivity and conductivity Materials Chemistry Ceramics and Composites Structure factor Electronic properties |
| Zdroj: | Journal of Non-Crystalline Solids. :245-249 |
| ISSN: | 0022-3093 |
| DOI: | 10.1016/s0022-3093(99)00231-8 |
| Popis: | We have carried out elastic neutron scattering measurements on the liquid equiatomic binary alloy K–Sb. The derived structure factor, S(Q), has a prepeak at about 1.1 A−1 indicative of large structural units. With increasing temperature to about 1800 K we find remarkably small changes in S(Q). We used the reverse Monte Carlo simulation method to explore details of the liquid structure in real space and found evidence to ascribe the prepeak in S(Q) to Sb–Sb correlations of Sb chain fragments. The electrical conductivity has a distinct increase from 0.8 to 40 Ω−1 cm−1 at T ≈ 825 K, and a conductivity of approximately 350 Ω−1 cm−1 is reached at 1673 K. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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