Synthesis of Sugar Isocyanates and Their Application to the Formation of Ureido-Linked Disaccharides

Autor: Juan C. Palacios, Martin Avalos, Mark E. Light, Reyes Babiano, Esther M. S. Pérez, Pedro Cintas, Michael B. Hursthouse, José L. Jiménez
Rok vydání: 2006
Předmět:
Zdroj: European Journal of Organic Chemistry. 2006:657-671
ISSN: 1099-0690
1434-193X
Popis: The present work describes a facile and practical route to carbohydrate-based isocyanates, a reactive and appealing family of chiral heterocumulenes, wich can be easily converted into disaccharides and pseudodisaccharides interconnected by urea moieties. A full characterization of these substances by X-ray diffraction analysis and spectroscopic methods reveals further insights into their structures and preferred conformation.
Databáze: OpenAIRE